Product ID:UNBRD PREM UNLEADED GASOLINE W/A
MSDS Date:09/11/1992
FSC:9150
NIIN:00B050036
MSDS Number: BHVPJ

EXXON COMPANY, USA, A DIV OF EXXON CORP.

800 BELL ST
HOUSTON, TX 77252-2180
US

Emergency Phone: 713-656-3424/2443 (MEDICAL)

Info Phone: 713-656-3631

Cage: DO850

EXXON COMPANY, USA, A DIV OF EXXON CORP.

2180 HOUSTON, TX 77252-2180 US

Telephone: 713-656-3631

Cage: DO850

NAPHTHA (PETROLEUM), LIGHT CATALYTIC CRACKED

CAS: 64741-55-5

NAPHTHA (PETROLEUM), HEAVY CATALYTIC CRACKED

CAS: 64741-54-4

NAPTHA (PETROLEUM), FULL-RANGE REFORMED

CAS: 68919-37-9

NAPTHA (PETROLEUM) FULL-RANGE ALKYLATE

CAS: 64741-64-6

NAPTHA (PETROLEUM) FULL-RANGE ALKYLATE

CAS: 64741-64-6

NAPTHA (PETROLEUM), SWEETENED

CAS: 64741-87-3

RTECS: EJ4200000

BUTANE

CAS: 106-97-8

RTECS: EJ4200000

OSHA PEL 300 PPM

ACGIH TLV: 800 PPM; 9192

LD50 LC50 Mixture:ORAL LD50 (RAT) IS >5G/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: MODERATE RISK OF VAPOR
INTOXICATION. MAJOR RISK IS ENCLOSED SPACES WITH POOR VENTILATION.
SKIN: DEFATTING WITH DRYING AND CRACKING CAN LEAD TO DERMATITIS AND
SECONDARY INFECTION. EYE: IRRI TANT. INGESTION: BURNING OF MOUTH
AND UPPER GI TRACT, VOMITING AND DIARRHEA. PROLONGED OR REPEATED
CONTACT: DERMATITIS.
Explanation of Carcinogenicity:API SPONSORED CHRONIC INHALATION STUDIES
OF UNLEADED GASOLINE VAPORS INDICATE THAT IT IS CARCINOGENIC TO LAB
ANIMALS.
Effects of Overexposure:INHALATION MAY CAUSE EUPHORIA, LUNG IRRITATION
AND EDEMA, HEADACHE, DIZZINESS, DROWSINESS, CONVULSIONS, COMA,
CYANOSIS, GENERALIZED DEPRESSION. INGESTION MAY CAUSE GENERAL
DEPRESSION, SEDATION, RESPIR ATORY DEPRESSION, COMA.
Medical Cond Aggravated by Exposure:PERSONNEL WITH PRE-EXISTING
DERMATITIS.

First Aid:EYES: FLUSH WITH RUNNING WATER FOR 15 MINUTES WHILE HOLDING
EYELIDS OPEN. SKIN: REMOVE CONTAMINATED CLOTHING. WASH SKIN WITH
SOAP AND WATER. INHALATION: REMOVE TO FRESH AIR. FOR RESPIRATORY
DISTRESS, GIVE AIR, OXYGEN, OR CPR IF NECESSARY. INGESTION: DO NOT
INDUCE VOMITING. KEEP HEAD BELOW HIPS IF VOMITING OCCURS TO PREVENT
ASPIRATION INTO LUNGS. GET MEDICAL ATTENTION IF REQUIRED IN ALL
CASES.

Flash Point:-36F,-38C
Lower Limits:1.4%
Upper Limits:7.6%
Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY
CHEMICAL.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED
CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE
HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS.

Spill Release Procedures:SMALL: TAKE UP WITH NON COMBUSTIBLE ABSORBENT
SUCH AS FULLERS EARTH OR SAND. PLACE INTO CONTAINERS FOR LATER
DISPOSAL. LARGE: CONTAIN SPILL IN EARTHEN DIKES FOR LATER RECOVERY.
CONTROL IGNITION SOURCE S AROUND SPILL AREA. REPORT SPILLS AS
REQUIRED.

Handling and Storage Precautions:AVOID STATIC IGNITION HAZARD WHEN
TRANSFERRING MATERIAL. KEEP CONTAINERS CLOSED AND AWAY FROM HEAT &
IGNITION SOURCES! DO NOT USE AS CLEANING AGENT.
Other Precautions:EMPTY CONTAINERS RETAIN SOME LIQUID/VAPOR RESIDUES;
HAZARD PRECAUTIONS MUST BE OBSERVED WHEN HANDLING EMPTIES. KEEP OUT
OF REACH OF CHILDREN! DO NOT USE ANY HYDROCARBON FUEL IN SPACES
WITHOUT ADEQUATE VENTILATION. USE ONLY AS A FUEL.

Respiratory Protection:A NIOSH/MSHA APPROVED ORGANIC VAPOR RESPIRATOR,
SUPPLIED AIR, OR SELF-CONTAINED BREATHING APPARATUS (SCBA) MUST BE
USED WHEN VAPOR CONCENTRATIONS EXCEED THE OCCUPATIONAL EXPOSURE
LIMITS.
Ventilation:USE ADEQUATE VENTILATION TO KEEP VAPOR CONCENTRATIONS OF
THIS MATERIAL BELOW THE OCCUPATIONAL EXPOSURE LIMITS.
Protective Gloves:WEAR OIL IMPERVIOUS (EG: NITRILE) GLOVES
Eye Protection:USE CHEMICAL SAFETY GOGGLES & FACESHIELD
Other Protective Equipment:OIL IMPERVIOUS INDUSTRIAL WORK CLOTHING TO
MINIMIZE SKIN CONTACT. EYE BATH AND SAFETY SHOWER RECOMMENDED.
Work Hygienic Practices:USE GOOD PERSONAL HYGIENE. USE WATERLESS HAND
CLEANER TO WASH EXPOSED SKIN. LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
THE VARIABLE COMPOSITION MAKES IT IMPOSSIBLE TO SET A SPECIFIC EXPOSURE
LIMIT FOR ALL COMPOSITIONS OF THIS MATERIAL. SPECIFIC EXPOSURE
LIMITS FOR POTENTIAL COMPONENTS SUCH AS BENZENE SHOULD BE APPLIED
BASED ON AIR MONITORING TO ASSURE EMPLOYEES ARE NOT EXPOSED TO
EXCESSIVE VAPOR LEVELS OF COMPONENTS.

Boiling Pt:B.P. Text:70.0F,21.1C
Vapor Pres:5-15 PSI
Vapor Density:APP 5
Spec Gravity:APP 0.74
pH:NEUTRL
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR COLORED LIQUID (TYPICALLY RED), GASOLINE
HYDROCARBON ODOR
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES
OF IGNITION
Hazardous Decomposition Products:BURNING OR EXCESSIVE HEATING MAY
PRODUCE CARBON MONOXIDE AND OTHER HARMFUL GASES/VAPORS.

Waste Disposal Methods:IT IS THE RESPONSIBILITY OF THE USER TO
DETERMINE IF THE MATERIAL IS A HAZARDOUS WASTE AT THE TIME OF
DISPOSAL. CHECK BEFORE DISPOSING TO BE SURE YOU ARE IN COMPLIANCE
WITH ALL APPLICABLE LAWS AND REG ULATIONS. CHEMTREC/RCRA EMER.
NO.:800-424-9346

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.